Lighting porphyrins and phthalocyanines for molecular photovoltaics

被引:606
作者
Victoria Martinez-Diaz, M. [1 ]
de la Torrea, Gema [1 ]
Torres, Tomas [1 ,2 ]
机构
[1] Univ Autonoma Madrid, Fac Ciencias, Dept Quim Organ, E-28049 Madrid, Spain
[2] IMDEA Nanociencia, Fac Ciencias, Madrid 28049, Spain
关键词
SENSITIZED SOLAR-CELLS; NANOCRYSTALLINE TIO2 FILMS; OPEN-CIRCUIT VOLTAGE; QUINOXALINE-FUSED PORPHYRINS; NEAR-IR SENSITIZATION; COPPER-PHTHALOCYANINE; ZINC PHTHALOCYANINE; ELECTRON INJECTION; ENERGY-CONVERSION; THIN-FILM;
D O I
10.1039/c0cc02213f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The field of organic photovoltaics (OPV) represents one of the most promising technological areas. Porphyrins and phthalocyanines are perfectly suited for their integration in light energy conversion systems. These colored macrocycles exhibit very attractive physical properties, particularly very high extinction coefficients in the visible and near IR regions, where the maximum of the solar photon flux occurs, that is necessary for efficient photon harvesting, besides a rich redox chemistry, as well as photoinduced electron transfer and semiconducting capabilities.
引用
收藏
页码:7090 / 7108
页数:19
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