Synthesis of crown-ester-bipyridines and crown-ester-viologens

被引：10
作者：
Bossmann, SH
Dürr, H
Pokhrel, MR
机构：
[1] Kansas State Univ, Dept Chem, Manhattan, KS 66506 USA
[2] Univ Saarland, Dept Chem, Sect Organ Chem, D-66041 Saarbrucken, Germany
[3] Tribhuvan Univ, Cent Dept Chem, Kathmandu, Nepal
来源：
SYNTHESIS-STUTTGART | 2005年 / 06期
关键词：
alkylations; bipyridines; esters; nickel(0); viologens;
D O I：
10.1055/s-2005-861829
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Six novel 4,4'-bipyridine-crown-esters, derived from [4,4']bipyridinyl-3,3'-dicarboxylic acid, [4,4']bipyridinyl-2,2'-dicarboxylic acid and [4,4']bipyridinyl-2,2',6,6'-tetra-carboxylic acid were synthesized employing a procedure closely related to the 'cesium carbonate method'. The 4,4'-bipyridine-crown-esters differ in their substitution positions of the aromatic bipyridine-units, as well as in the geometric extensions of their crown-ester moieties. Addition of 1,3-propane sultone to the 4,4'-bipyridine-crown-esters resulted in five novel propanesultonated 4,4'-bipyridine-crown-esteiviologens.
引用
收藏
页码：907 / 914
页数：8
相关论文
共 37 条
[1]   Photoinduced electron transfer and intramolecular folding in a tricarbonylrhenium (bi)pyridine based donor/crown/acceptor assembly: Dependence on solvent [J].
BergBrennan, CA ;
Yoon, DI ;
Slone, RV ;
Kazala, AP ;
Hupp, JT .
INORGANIC CHEMISTRY, 1996, 35 (07) :2032-2035
[2]   SUPRAMOLECULAR SENSITIZER RELAY ASSEMBLIES - AN EVALUATION OF BINDING CONSTANTS FROM NONLINEAR STERN-VOLMER PLOTS [J].
BOSSMAN, S ;
SEILER, M ;
DURR, H .
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1992, 5 (02) :63-73
[3]   FUNCTIONALIZED DITHIA-CROWNS AND TETRATHIA-CROWNS AND THEIR USE TO QUANTITATIVELY SEPARATE AND RECOVER GOLD(III), PALLADIUM(II), SILVER(I) AND MERCURY(II) IONS [J].
BRADSHAW, JS ;
KRAKOWIAK, KE ;
IZATT, RM ;
BRUENING, RL ;
TARBET, BJ .
JOURNAL OF HETEROCYCLIC CHEMISTRY, 1990, 27 (02) :347-349
[4]   Chiral 2,2′-bipyridines, 1,10-phenanthrolines, and 2,2′:6′,2"-terpyridines:: Syntheses and applications in asymmetric homogeneous catalysis [J].
Chelucci, G ;
Thummel, RP .
CHEMICAL REVIEWS, 2002, 102 (09) :3129-3170
[5]   Photochemical ion receptor based on a structurally distorted ruthenium(II) complex having a crown-ether moiety at the 3,3'-positions on the 2,2'-bipyridine ligand [J].
Chiba, M ;
Kim, HB ;
Kitamura, N .
ANALYTICAL SCIENCES, 2002, 18 (04) :461-466
[6]  
Chiba M, 2001, CHEM LETT, P692
[7]   SUPRAMOLECULAR EFFECTS ON PHOTOCHROMISM - PROPERTIES OF CROWN ETHER-MODIFIED DIHYDROINDOLIZINES [J].
DURR, H ;
THOME, A ;
KRANZ, C ;
KILBURG, H ;
BOSSMANN, S ;
BRAUN, B ;
JANZEN, KP ;
BLASIUS, E .
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1992, 5 (10) :689-698
[8]   Ruthenium polypyridine complexes.: On the route to biomimetic assemblies as models for the photosynthetic reaction center [J].
Dürr, H ;
Bossmann, S .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (11) :905-917
[9]  
DURR H, 1990, SYNTHESIS-STUTTGART, P773
[10]  
DURR H, 1991, FRONTIERS SUPRAMOLEC
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