Zirconium and titanium complexes with side-chain functionalized cyclopentadienyl ligands

被引：9

作者：

Krut'ko, D. P. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2009年 / 58卷 / 09期

关键词：

zirconium; titanium; side-chain functionalized cyclopentadienyl ligands; reduction reactions; activation of unreactive bonds; dynamic behavior in solution; NMR spectroscopy; SUBSTITUTED ZIRCONOCENE DICHLORIDES; REDUCTIVE ELIMINATION-REACTIONS; CRYSTAL-STRUCTURE; CATALYTIC HYDROAMINATION; DINITROGEN COMPLEXES; DYNAMIC-BEHAVIOR; BOND ACTIVATION; PENDANT ETHER; BEARING; HYDROGENATION;

D O I：

10.1007/s11172-009-0242-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The present review summarizes the results of studies of Zr and Ti complexes based on chelating side-chain functionalized cyclopentadienyl ligands, which were synthesized by the author of the present review and co-workers. The coordination ability of the functional groups is considered. Dynamic processes that occur in half-sandwich complexes in solutions were studied by NMR spectroscopy. Emphasis is given to the reduction reactions of side-chain functionalized zirconocene dichlorides, as well as to the structures and properties of the reaction products depending on the nature of the heteroatomic substituent.

引用

页码：1745 / 1771

页数：27

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