Charge-assisted N-H•••I and C-H•••I hydrogen bonding in (1R,2S)-1-(ferrocenylmethyl)-2-(methoxymethyl)pyrrolidinium iodide

被引:11
作者
Palusiak, M
Janowska, I
Zakrzewski, J
Grabowski, SJ
机构
[1] Univ Lodz, Dept Crystallog & Crystal Chem, PL-90236 Lodz, Poland
[2] Univ Lodz, Dept Organ Chem, PL-90136 Lodz, Poland
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2005年 / 61卷
关键词
D O I
10.1107/S0108270104027581
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the title compound, [Fe(C5H5)(C12H19NO)] I, the ferrocene moiety has an eclipsed conformation, with mean Fe - C bond lengths of 2.031 ( 4) and 2.020 ( 6) Angstrom for the substituted and unsubstituted cyclopentadienyl rings. The pyrrolidinium heterocycle adopts an envelope conformation and has its 1- and 2-substituents in a relative trans disposition. Strong (+/-)-charge- assisted N - H ... I and C - H ... I hydrogen bonds are present. The crystal structure is also stabilized by weak C H ... O interactions.
引用
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页码:M55 / M57
页数:3
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