Green and catalyst-free synthesis of aminoanthraquinone derivatives in solvent-free conditions

被引：1

作者：

Sardashti-Birjandi, Arezoo ^{[1
]}

Mollashahi, Ebrahim ^{[1
]}

Maghsoodlou, Malek Taher ^{[1
]}

Yazdani-Elah-Abadi, Afshin ^{[2
]}

机构：

[1] Univ Sistan & Baluchestan, Fac Sci, Dept Chem, POB 98135-674, Zahedan, Iran

[2] Islamic Azad Univ, Yazd Branch, Young Researchers & Elite Club, Yazd, Iran

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2021年 / 47卷 / 09期

关键词：

Multicomponent reactions; Anthraquinone; Catalyst-free; Triethyl orthoformate; ONE-POT SYNTHESIS; ANTHRAQUINONE DERIVATIVES; REUSABLE CATALYST; DEGRADATION; NANOCOMPOSITE; DYES; CHEMISTRY; EFFICIENT; REMOVAL; MEDIA;

D O I：

10.1007/s11164-021-04485-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this study, new derivatives of aminoanthraquinone have been synthesized via one-pot three-component condensation reaction of 1- and 2-amino anthraquinones, triethyl orthoformate and CH-acid compounds without using any solvent or catalyst in mild temperature (50 degrees C). This simple and efficient method yields the desired products in short reaction time (14-50 min) and good to excellent yields (85-96%). Moreover, chemical structures of synthesized products have been entirely confirmed by FT-IR, H-1 and (CNMR)-C-13 and mass spectroscopy and melting points.

引用

页码：3597 / 3608

页数：12

共 57 条

[1] Identification of anthraquinone coloring matters in natural red dyestuffs by high performance liquid chromatography with ultraviolet and electrospray mass spectrometric detection
Ackacha, MA
Polec-Pawlak, K
Jarosz, M
[J]. JOURNAL OF SEPARATION SCIENCE, 2003, 26 (11) : 1028 - 1034
[2] Utilizing an Old Idea for the Three-Component Synthesis of Anthraquinone-Scaffold-Based Enaminodiones (2,2-Diacylethenamines)
Aelami, Zahra
Maghsoodlou, Malek Taher
Heydari, Reza
Yazdani-Elah-Abadi, Afshin
[J]. POLYCYCLIC AROMATIC COMPOUNDS, 2022, 42 (02) : 582 - 592
[3] Three-Component Synthesis of Tetrazolo Anthraquinone as a Representation of a New Heterocyclic System
Aelami, Zahra
Maghsoodlou, Malek Taher
Heydari, Reza
[J]. CHEMISTRYSELECT, 2019, 4 (18): : 5315 - 5318
[4] Green synthesis of nanostructure Schiff base complex based on aromatic polyamide and manganese(III) for elimination of Hg(II) and Cd(II) from solutions
Aghaei, Marjan
Kianfar, Ali Hossein
Dinari, Mohammad
[J]. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2019, 16 (11) : 2489 - 2500
[5] Rice Husk and Its Ash as Low-Cost Adsorbents in Water and Wastewater Treatment
Ahmaruzzaman, M.
Gupta, Vinod K.
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (24) : 13589 - 13613
[6] An efficient and eco-friendly synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes using H4[SiW12O40] as a heterogeneous and reusable catalyst under solvent-free conditions
Allameh, S.
Davoodnia, A.
Khojastehnezhad, A.
[J]. CHINESE CHEMICAL LETTERS, 2012, 23 (01) : 17 - 20
[7] Green Chemistry: Principles and Practice
Anastas, Paul
Eghbali, Nicolas
[J]. CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) : 301 - 312
[8] Origins, current status, and future challenges of green chemistry
Anastas, PT
Kirchhoff, MM
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (09) : 686 - 694
[9] [Anonymous], 2013, Alternative Solvents for Green Chemistry
[10] Anti-human cytomegalovirus activity and toxicity of sulfonated anthraquinones and anthraquinone derivatives
Barnard, DL
Fairbairn, DW
ONeill, KL
Gage, TL
Sidwell, RW
[J]. ANTIVIRAL RESEARCH, 1995, 28 (04) : 317 - 329

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