Photoinitiated polymerization of β-cyclodextrin/methyl methacrylate host/guest complex in the presence of water soluble photoinitiator, thioxanthone-catechol-O,O'-diacetic acid

被引：6

作者：

Karasu, Feyza ^{[1
]}

Balta, Demet Karaca ^{[1
]}

Liska, Robert ^{[2
]}

Arsu, Nergis ^{[1
]}

机构：

[1] Yildiz Tech Univ, Dept Chem, TR-34210 Istanbul, Turkey

[2] Vienna Univ Technol, Inst Appl Synthet Chem, A-1040 Vienna, Austria

来源：

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2010年 / 68卷 / 1-2期

关键词：

Photopolymerization; Free radical polymerization; beta-Cyclodextrin; Thioxanthone; Water soluble photoinitiator; FREE-RADICAL POLYMERIZATION; METHYL-METHACRYLATE; AQUEOUS PHOTOPOLYMERIZATION; THIOXANTHONE; STYRENE; UNITS;

D O I：

10.1007/s10847-010-9760-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

beta-Cyclodextrin (beta-CD) was used to complex the monomer, methyl methacrylate (MMA), yielding a water-soluble host/guest complex. Photoinitiated polymerization of beta-CD/MMA complex was achieved in the presence of thioxanthone-catechol-O,O'-diacetic acid (TX-Ct), a one component water soluble photoinitiator. Photodecarboxylation of TX-Ct in water seems to be an important reaction mechanism. Therefore, resulting alkyl radicals are able to initiate the polymerization of beta-CD/MMA host/guest complex in water.

引用

页码：147 / 153

页数：7

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