Selective CO2 gas adsorption in the narrow crystalline cavities of flexible peptide metallo-macrocycles

被引：12

作者：

Miyake, Ryosuke ^{[1
]}

Kuwata, Chika ^{[1
]}

Masumoto, Yui ^{[1
]}

机构：

[1] Ochanomizu Univ, Grad Sch Humanities & Sci, Dept Chem & Biochem, Bunkyo Ku, Tokyo 1128610, Japan

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 07期

关键词：

SIDE-CHAIN CONTROL; POROUS MATERIALS; COORDINATION POLYMER; LIGAND-EXCHANGE; CARBON-DIOXIDE; CAPTURE; HOST; HYDROGEN; STIMULI; BINDING;

D O I：

10.1039/c4dt03530e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystalline peptide Ni(II)-macrocycles (BF4- salt) exhibited moderate CO2 gas adsorption (ca. 6-7 CO2 molecules per macrocycle) into very narrow cavities (narrowest part <2 angstrom), accompanied by the expansion of the cavities. The BF4- salt demonstrated selective uptake of CO2 gas in preference to CH4 and N-2 gases.

引用

页码：2993 / 2996

页数：4

共 33 条

[31] Spontaneous and Selective CO2 Sorption under Ambient Conditions in Seemingly Nonporous Molecular Crystal of Azacalix[5]arene Pentamethyl Ether [J].

Tsue, Hirohito ;

Ono, Kohei ;

Tokita, Satoshi ;

Ishibashi, Koichi ;

Matsui, Kazuhiro ;

Takahashi, Hiroki ;

Miyata, Kazuyuki ;

Takahashi, Daisuke ;

Tamura, Rui .

ORGANIC LETTERS, 2011, 13 (03) :490-493

[32] Direct Observation and Quantification of CO2 Binding Within an Amine-Functionalized Nanoporous Solid [J].

Vaidhyanathan, Ramanathan ;

Iremonger, Simon S. ;

Shimizu, George K. H. ;

Boyd, Peter G. ;

Alavi, Saman ;

Woo, Tom K. .

SCIENCE, 2010, 330 (6004) :650-653

[33] A flexible MMOF exhibiting high selectivity for CO2 over N2, CH4 and other small gases [J].

Zhang, Jingming ;

Wu, Haohan ;

Emge, Thomas J. ;

Li, Jing .

CHEMICAL COMMUNICATIONS, 2010, 46 (48) :9152-9154

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