Selective CO2 gas adsorption in the narrow crystalline cavities of flexible peptide metallo-macrocycles

被引：12
作者：
Miyake, Ryosuke [1 ]
Kuwata, Chika [1 ]
Masumoto, Yui [1 ]
机构：
[1] Ochanomizu Univ, Grad Sch Humanities & Sci, Dept Chem & Biochem, Bunkyo Ku, Tokyo 1128610, Japan
来源：
DALTON TRANSACTIONS | 2015年 / 44卷 / 07期
关键词：
SIDE-CHAIN CONTROL; POROUS MATERIALS; COORDINATION POLYMER; LIGAND-EXCHANGE; CARBON-DIOXIDE; CAPTURE; HOST; HYDROGEN; STIMULI; BINDING;
D O I：
10.1039/c4dt03530e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Crystalline peptide Ni(II)-macrocycles (BF4- salt) exhibited moderate CO2 gas adsorption (ca. 6-7 CO2 molecules per macrocycle) into very narrow cavities (narrowest part <2 angstrom), accompanied by the expansion of the cavities. The BF4- salt demonstrated selective uptake of CO2 gas in preference to CH4 and N-2 gases.
引用
收藏
页码：2993 / 2996
页数：4
相关论文
共 33 条
[1]   High and Selective CO2 Uptake in a Cobalt Adeninate Metal-Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores [J].
An, Jihyun ;
Geib, Steven J. ;
Rosi, Nathaniel L. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (01) :38-+
[2]   A new type of material for the recovery of hydrogen from gas mixtures [J].
Atwood, JL ;
Barbour, LJ ;
Jerga, A .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (22) :2948-2950
[3]   Guest transport in a nonporous organic solid via dynamic van der Waals cooperativity [J].
Atwood, JL ;
Barbour, LJ ;
Jerga, A ;
Schottel, BL .
SCIENCE, 2002, 298 (5595) :1000-1002
[4]   A crystalline organic substrate absorbs methane under STP conditions [J].
Atwood, JL ;
Barbour, LJ ;
Thallapally, PK ;
Wirsig, TB .
CHEMICAL COMMUNICATIONS, 2005, (01) :51-53
[5]   Storage of methane and freon by interstitial van der Waals confinement [J].
Atwood, JL ;
Barbour, LJ ;
Jerga, A .
SCIENCE, 2002, 296 (5577) :2367-2369
[6]   Design, chirality, and flexibility in nanoporous molecule-based materials [J].
Bradshaw, D ;
Claridge, JB ;
Cussen, EJ ;
Prior, TJ ;
Rosseinsky, MJ .
ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :273-282
[7]   Mechanical gas capture and release in a network solid via multiple single-crystalline transformations [J].
Chandler, Brett D. ;
Enright, Gary D. ;
Udachin, Konstantin A. ;
Pawsey, Shane ;
Ripmeester, John A. ;
Cramb, David T. ;
Shimizu, George K. H. .
NATURE MATERIALS, 2008, 7 (03) :229-235
[8]   Methane, carbon dioxide and hydrogen storage in nanoporous dipeptide-based materials [J].
Comotti, Angiolina ;
Bracco, Silvia ;
Distefano, Gaetano ;
Sozzani, Piero .
CHEMICAL COMMUNICATIONS, 2009, (03) :284-286
[9]   Engineering void space in organic van der Waals crystals: calixarenes lead the way [J].
Dalgarno, Scott J. ;
Thallapally, Praveen K. ;
Barbour, Leonard J. ;
Atwood, Jerry L. .
CHEMICAL SOCIETY REVIEWS, 2007, 36 (02) :236-245
[10]   Strong CO2 Binding in a Water-Stable, Triazolate-Bridged Metal-Organic Framework Functionalized with Ethylenediamine [J].
Demessence, Aude ;
D'Alessandro, Deanna M. ;
Foo, Maw Lin ;
Long, Jeffrey R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (25) :8784-+
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