Free radical and RAFT polymerization of vinyl esters in metal-organic-frameworks

被引：57
作者：
Hwang, Jongkook [1 ]
Lee, Hui-Chun [1 ]
Antonietti, Markus [1 ]
Schmidt, Bernhard V. K. J. [1 ]
机构：
[1] Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, Muhlenberg 1, D-14476 Potsdam, Germany
来源：
POLYMER CHEMISTRY | 2017年 / 8卷 / 40期
关键词：
POROUS COORDINATION POLYMERS; MOLECULAR-WEIGHT; ACETATE; STEREOCHEMISTRY; FLUOROALCOHOLS; CHANNELS;
D O I：
10.1039/c7py01607g
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Free radical and RAFT polymerization of vinyl esters with different molecular dimensions are conducted in the nanochannels of metal-organic-frameworks (MOFs). The combination of MOFs with the RAFT technique enables the synthesis of highly isotactic poly(vinyl ester)s with a controlled molecular weight and narrow molecular weight distribution, and stereocontrolled isotactic-block-atactic vinyl ester block copolymers.
引用
收藏
页码：6204 / 6208
页数：5
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