A NEW SYNTHETIC STRATEGY FOR 2-DEOXY-D-RIBOSE VIA PALLADIUM(II)-CATALYZED CYCLIZATION OF ALDEHYDE

被引：5
|
作者：
Miyazawa, Masahiro [1 ]
Awasaguchi, Ken-ichiro [1 ]
Uoya, Ikuyo [1 ]
Yokoyama, Hajime [1 ]
Hirai, Yoshiro [1 ]
机构：
[1] Toyama Univ, Grad Sch Sci & Technol, Toyama 9308555, Japan
来源：
HETEROCYCLES | 2010年 / 81卷 / 08期
关键词：
Carbohydrate; Hemiacetal; Tetrahydropyran; Stereoselectivity; Anomeric Effect; STEREOCONTROLLED CYCLIZATION; N-ALKYLATION; CONSTRUCTION; URETHANES; EFFICIENT; AGENTS; ACID;
D O I：
10.3987/COM-10-11988
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We achieved a total synthesis of 2-deoxy-D-ribose through intramolecular Pd(II)-catalyzed cyclization of aldehyde via an unstable hemiacetal intermediate as a key step.
引用
收藏
页码：1891 / 1902
页数：12
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