Pb5In3Bi5S17 [Pb4.94(3)In3.05(3)Bi4.99(3)S17] and its structural relationship with Pb4In3Bi7S18

被引：0
|
作者：
Winkler, H. P. [1 ]
Topa, D. [2 ]
Keller, E. [1 ]
机构：
[1] Univ Freiburg, Inst Geowissensch, D-79104 Freiburg, Germany
[2] Salzburg Univ, Fachbereich Mat Forsch & Phys, A-5020 Salzburg, Austria
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2012年 / 68卷
关键词：
INDIUM BISMUTH CHALCOGENIDES; CRYSTAL-STRUCTURE; PHASE; SULFIDES; SYSTEM;
D O I：
10.1107/S0108270112021865
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title phase (pentalead triindium pentabismuth heptadecasulfide) has been synthesized and structurally characterized. Its structure contains mixed Bi/In, In/Bi and Pb/In positions; all atoms lie on crystallographic mirror planes. The structural relationship between Pb5In3Bi5S17 and a phase known by the formula Pb4In3Bi7S18 is discussed. A comparatively large and complex structural `seed' is defined which is common to both phases. The structural changes within this seed when moving from one phase to the other are described by graphical means.
引用
收藏
页码：I45 / I49
页数：5
相关论文
共 50 条
  • [21] Ultralow Lattice Thermal Conductivity in the Aikinite Structure Family, CuXPbXBi2-XS3, and Thermoelectric Properties of Cu0.14Pb0.14Bi1.86S3
    Balijapelly, Srikanth
    Hauble, Ashlee
    Sundaramoorthy, Santhoshkumar
    Watts, Jeremy Lee
    Kauzlarich, Susan M.
    Chernatynskiy, Aleksandr
    Choudhury, Amitava
    ACS APPLIED ENERGY MATERIALS, 2022, 5 (11) : 14222 - 14230
  • [22] Influence of 6s2 lone pair electrons of Bi3+ on its preferential site occupancy in fluorapatite, NaCa3Bi(PO 4)3F - An insight from Eu3+ luminescent probe
    Lakshminarasimhan, N.
    Varadaraju, U.V.
    Materials Research Bulletin, 2014, 60
  • [23] Local and Permeating Disorder of Copper(I) Cations in Cu3BiS2Br2 and Cu4Bi3S5Br3-xClx (x=1.19)
    Heerwig, Andreas
    Nitsche, Fabian
    Ruck, Michael
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2011, 637 (01): : 62 - 66
  • [24] [Bi3GaS5]2[Ga3Cl10]2[GaCl4]2•S8 containing heterocubane-type [Bi3GaS5]2+, star-shaped [Ga3Cl10]-, monomeric [GaCl4]- and crown-like S8
    Freudenmann, Dominic
    Feldmann, Claus
    DALTON TRANSACTIONS, 2011, 40 (02) : 452 - 456
  • [25] Bi(S2CNC5H10)2(NO3)(1,10-phenanthroline)
    Yin, HD
    Wang, CH
    APPLIED ORGANOMETALLIC CHEMISTRY, 2004, 18 (04) : 195 - 196
  • [26] Influence of 6s2 lone pair electrons of Bi3+ on its preferential site occupancy in fluorapatite, NaCa3Bi(PO4)3F - An insight from Eu3+ luminescent probe
    Lakshminarasimhan, N.
    Varadaraju, U. V.
    MATERIALS RESEARCH BULLETIN, 2014, 60 : 238 - 241
  • [27] Glass transition (Tg) and dielectric constant (εr′) of Li3PO4-Pb3(PO4)2-BiPO4 (Li2O-Pbo-Bi2O3-P2O5) glasses
    Elmoudane, M
    Belkhouaja, M
    Et-Tabirou, M
    Taibi, M
    PHASE TRANSITIONS, 2003, 76 (07) : 645 - 652
  • [28] Lead-antimony sulfosalts from Tuscany (Italy).: IV.: Crystal structure of pillaite, Pb9Sb10S23ClO0.5, an expanded monoclinic derivative of hexagonal Bi(Bi2S3)9I3, from the zinkenite group
    Meerschaut, A
    Palvadeau, P
    Moëlo, Y
    Orlandi, P
    EUROPEAN JOURNAL OF MINERALOGY, 2001, 13 (04) : 779 - 790
  • [29] Holubite, Ag3Pb6(Sb8Bi3)Σ11S24, from Kutna Hora, Czech Republic, a new member of the andorite branch of the lillianite homologous series
    Pazout, Richard
    Plasil, Jakub
    Dusek, Michal
    Sejkora, Jiri
    Dolnicek, Zdenek
    MINERALOGICAL MAGAZINE, 2023, 87 (04) : 582 - 590
  • [30] STRUCTURAL-ANALYSIS AND SUPERCONDUCTING PROPERTIES OF PB-FREE BI2SR2CA3CU4OY (N = 4, NOMINAL COMPOSITION)
    LOSCH, S
    BUDIN, H
    EIBL, O
    HARTMANN, M
    RENTSCHLER, T
    RYGULA, M
    KEMMLERSACK, S
    HUEBENER, RP
    PHYSICA C, 1991, 177 (4-6): : 271 - 280
12345