Pb5In3Bi5S17 [Pb4.94(3)In3.05(3)Bi4.99(3)S17] and its structural relationship with Pb4In3Bi7S18

被引：0
|
作者：
Winkler, H. P. [1 ]
Topa, D. [2 ]
Keller, E. [1 ]
机构：
[1] Univ Freiburg, Inst Geowissensch, D-79104 Freiburg, Germany
[2] Salzburg Univ, Fachbereich Mat Forsch & Phys, A-5020 Salzburg, Austria
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2012年 / 68卷
关键词：
INDIUM BISMUTH CHALCOGENIDES; CRYSTAL-STRUCTURE; PHASE; SULFIDES; SYSTEM;
D O I：
10.1107/S0108270112021865
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title phase (pentalead triindium pentabismuth heptadecasulfide) has been synthesized and structurally characterized. Its structure contains mixed Bi/In, In/Bi and Pb/In positions; all atoms lie on crystallographic mirror planes. The structural relationship between Pb5In3Bi5S17 and a phase known by the formula Pb4In3Bi7S18 is discussed. A comparatively large and complex structural `seed' is defined which is common to both phases. The structural changes within this seed when moving from one phase to the other are described by graphical means.
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页码：I45 / I49
页数：5
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