Supramolecular aggregation patterns based on the bio-inspired Se(lone pair) ... π(aryl) synthon

被引:39
作者
Caracelli, Ignez [1 ]
Zukerman-Schpector, Julio [2 ]
Tiekink, Edward R. T. [3 ]
机构
[1] Univ Fed Sao Carlos, Dept Fis, BR-13565905 Sao Paulo, Brazil
[2] Univ Fed Sao Carlos, Dept Quim, Lab Cristalog Estereodinam & Modelagem Mol, BR-13565905 Sao Paulo, Brazil
[3] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
基金
巴西圣保罗研究基金会;
关键词
Selenium(II)/(IV); Supramolecular association; Lone pair(sic)pi interaction; Selenium-containing biomolecules; RAY CRYSTAL-STRUCTURES; CAMBRIDGE STRUCTURAL DATABASE; NMR CHEMICAL-SHIFTS; DOT-PI-INTERACTIONS; SE-C ATOMS; MOLECULAR-STRUCTURE; LONE-PAIR; AROMATIC RINGS; DISELENADIAZOLYL RADICALS; CRYSTALLOGRAPHIC ANALYSIS;
D O I
10.1016/j.ccr.2011.10.021
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Consistent with macromolecular structures. Se(lone pair)(sic)pi(aryl) interactions are found in the crystal structures of molecular compounds. Supramolecular aggregation patterns based solely on these types of interactions were usually zero- or one-dimensional with a smaller number of examples of two- and three-dimensional architectures. The analysis proves that Se(lone pair)(sic)pi(aryl) interactions function as supramolecular synthons in the structural chemistry of selenium compounds. (c) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:412 / 438
页数:27
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