Radiation grafting of N,N′-dimethylacrylamide and N-isopropylacrylamide onto polypropylene films by two-step method

被引：37
|
作者：
Contreras-Garcia, A. [1 ]
Burillo, G. [1 ]
Aliev, R. [1 ]
Bucio, E. [1 ]
机构：
[1] Univ Nacl Autonoma Mexico, Inst Ciencias Nucl, Dept Quim Radiac & Radioquim, Mexico City 04510, DF, Mexico
来源：
RADIATION PHYSICS AND CHEMISTRY | 2008年 / 77卷 / 08期
关键词：
polypropylene; N; '-dimethylacrylamide; N-isopropylacrylamide; radiation grafting; LCST;
D O I：
10.1016/j.radphyschem.2008.02.007
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Polypropylene (PP) films were modified by the consecutive grafting of N, N'-dimethylacrylamide (DMAAm) and N-isopropylacrylamide (NIPAAm) (two-step method) using preirradiation method with gamma-rays. The effect of absorbed dose, monomer concentration and reaction time on the degree of grafting was determined. The grafted samples were verified by the FTIR-ATR spectroscopy; thermal properties were analyzed by differential scanning calorimetry (DSC) and the stimuli-responsive behavior was studied by swelling and contact angle in water as well as DSC. Thermoresponsive films of (PP-g-DMAAm)-g-NIPAAm. presented a lower critical solution temperature (LCST) at 36.5 degrees C. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：936 / 940
页数：5
相关论文
共 50 条
  • [31] Preparation of alginate/poly(N-isopropylacrylamide) hydrogels using gamma-ray irradiation grafting
    Lee, SB
    Seo, SM
    Lim, YM
    Cho, SK
    Lee, YM
    Nho, YC
    MACROMOLECULAR RESEARCH, 2004, 12 (03) : 269 - 275
  • [32] The Preparation and Properties of Thermosensitive Hydrogels Based on Chitosan Grafted N-isopropylacrylamide via γ-Radiation
    Hong CAI1
    ChineseChemicalLetters, 2004, (10) : 1253 - 1254
  • [33] Gama radiation-induced graft copolymerization of N-p-hydroxyphenylmaleimide onto polypropylene films
    Samia M. Mokhtar
    Tahia B. Mostafa
    Journal of Polymer Research, 2000, 7 : 215 - 219
  • [34] Gama radiation-induced graft copolymerization of N-p-hydroxyphenylmaleimide onto polypropylene films
    Mokhtar, SM
    Mostafa, TB
    JOURNAL OF POLYMER RESEARCH-TAIWAN, 2000, 7 (04): : 215 - 219
  • [35] The preparation and properties of thermosensitive hydrogels based on chitosan grafted N-isopropylacrylamide via γ-radiation
    Cai, H
    Zhang, J
    Zhang, ZP
    Zhang, YG
    He, BL
    CHINESE CHEMICAL LETTERS, 2004, 15 (10) : 1253 - 1254
  • [36] Simultaneously occurring process of radiation-induced polymerization, crosslinking, and degradation of N-isopropylacrylamide
    Nagaoka, N
    Yoshida, M
    Asano, M
    Suwa, T
    Kubota, H
    Katakai, R
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1997, 35 (14) : 3075 - 3077
  • [37] Fabrication of thermo-responsive nano-valve by grafting-to in melt of poly(N-isopropylacrylamide) onto nanoporous silicon nitride membranes
    Bojko, Alexandre
    Andreatta, Gaelle
    Montagne, Franck
    Renaud, Philippe
    Pugin, Raphael
    JOURNAL OF MEMBRANE SCIENCE, 2014, 468 : 118 - 125
  • [38] PULSED NMR-STUDY OF RADIATION POLYMERIZATION AND CROSS-LINKING OF N-ISOPROPYLACRYLAMIDE
    SAFRANJ, A
    YOSHIDA, M
    OMICHI, H
    KATAKAI, R
    RADIATION PHYSICS AND CHEMISTRY, 1995, 46 (4-6): : 987 - 990
  • [39] Swelling and Thermoresponsive Behavior of Linear versus Cyclic Poly(N-isopropylacrylamide) Thin Films
    Magerl, David
    Philipp, Martine
    Qiu, Xing-Ping
    Winnik, Francoise M.
    Mueller-Buschbaum, Peter
    MACROMOLECULES, 2015, 48 (09) : 3104 - 3111
  • [40] Radiation-grafting of thermo- and pH-responsive poly (N-vinylcaprolactam-co-acrylic acid) onto silicone rubber and polypropylene films for biomedical purposes
    Ferraz, Caroline C.
    Varca, Gustavo H. C.
    Ruiz, Juan-Carlos
    Lopes, Patricia S.
    Mathor, Monica B.
    Lugao, Ademar B.
    Bucio, Emilio
    RADIATION PHYSICS AND CHEMISTRY, 2014, 97 : 298 - 303
12345