Zeolite-fiber integrated optical chemical sensors for detection of dissolved organics in water

被引:45
作者
Zhang, J
Dong, JH
Luo, M
Xiao, H [1 ]
Murad, S
Normann, RA
机构
[1] New Mexico Inst Min & Technol, Dept Elect Engn, Socorro, NM 87801 USA
[2] New Mexico Inst Min & Technol, Dept Petr & Chem Engn, Socorro, NM 87801 USA
[3] New Mexico Inst Min & Technol, New Mexico Petr Recovery Res Ctr, Socorro, NM 87801 USA
[4] Univ Illinois, Dept Chem Engn, Chicago, IL 60607 USA
[5] Sandia Natl Labs, Geothermal Res Div, Albuquerque, NM 87185 USA
关键词
D O I
10.1021/la0514967
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
MFI zeolite coated optical fiber sensors have been developed for in situ detection of dissolved organics in water. The sensors operate by monitoring the optical reflectivity changes caused by the selective adsorption of organic molecules, i.e., 2-propanol or pentanoic acid in this study, from aqueous solutions in the zeolitic pores. Reversible and monotonic sensor signals were observed in response to the variation of 2-propanol concentration in water with fast response. However, the sensor exhibited a much slower response to pentanoic acid than to 2-propanol. It was also found that substitution of Si by Al in the MFI framework increased the adsorption of pentanoic acid that resulted in enhanced sensor responses.
引用
收藏
页码:8609 / 8612
页数:4
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