Copper-catalyzed direct acyloxylation of C(sp2)-H bonds with Benzoic acids

被引：23
|
作者：
Zhao, Sheng [1 ]
Chen, Fa-Jie [1 ]
Liu, Bin [1 ]
Shi, Bing-Feng [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China
来源：
SCIENCE CHINA-CHEMISTRY | 2015年 / 58卷 / 08期
基金：
中国国家自然科学基金;
关键词：
copper; C-H activation; acyloxylation; ester; bidentate; UNACTIVATED C(SP(3))-H; FUNCTIONALIZATIONS; ETHERIFICATION; ARYLATION; OXIDATION; ARENES;
D O I：
10.1007/s11426-015-5376-z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A copper-catalyzed acyloxylation of C(sp(2))-H bond with sterically bulky benzoic acids was achieved. This protocol is compatible with a broad range of functional groups and could proceed in gram scale, providing an efficient and practical protocol for the synthesis of aryl esters.
引用
收藏
页码：1302 / 1309
页数：8
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