Low-Temperature Chemical Vapor Deposition Synthesis of Pt-Co Alloyed Nanoparticles with Enhanced Oxygen Reduction Reaction Catalysis

被引：165
作者：
Choi, Dong Sung [1 ]
Robertson, Alex W. [2 ]
Warner, Jamie H. [2 ]
Kim, Sang Ouk [1 ]
Kim, Heeyeon [3 ]
机构：
[1] Korea Adv Inst Sci & Technol, Natl Creat Res Initiat Ctr Multidimens Directed N, Dept Mat Sci & Engn, 291 Daehak Ro, Daejeon 34141, South Korea
[2] Univ Oxford, Dept Mat, Parks Rd, Oxford OX1 3PH, England
[3] Korea Inst Energy Res, Energy Mat Lab, 152 Gajeong Ro, Daejeon 34129, South Korea
来源：
ADVANCED MATERIALS | 2016年 / 28卷 / 33期
关键词：
HIGH ELECTROCATALYTIC ACTIVITY; PARTICLE-SIZE; FUEL-CELLS; CARBON NANOTUBES; METAL NANOPARTICLES; SURFACE-COMPOSITION; SUPPORTED PLATINUM; ELECTROLYTE; GRAPHENE; NITROGEN;
D O I：
10.1002/adma.201600469
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Novel Pt-Co alloyed nanocatalysts are generated via chemical vapor deposition-assisted facile one-pot synthesis. The method guarantees highly monodisperse Pt-Co alloy nanoparticles with precise control of metallic compositions within 1 at%. A significant features is that a perfectly alloyed single-crystal structure is obtained at temperatures as low as 500 degrees C, which is much lower than conventional alloying temperatures.
引用
收藏
页码：7115 / +
页数：9
相关论文
共 86 条
  • [61] Improved oxygen reduction activity on Pt3Ni(111) via increased surface site availability
    Stamenkovic, Vojislav R.
    Fowler, Ben
    Mun, Bongjin Simon
    Wang, Guofeng
    Ross, Philip N.
    Lucas, Christopher A.
    Markovic, Nenad M.
    [J]. SCIENCE, 2007, 315 (5811) : 493 - 497
  • [62] Effect of surface composition on electronic structure, stability, and electrocatalytic properties of Pt-transition metal alloys: Pt-skin versus Pt-skeleton surfaces
    Stamenkovic, Vojislav R.
    Mun, Bongjin Simon
    Mayrhofer, Karl J. J.
    Ross, Philip N.
    Markovic, Nenad M.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (27) : 8813 - 8819
  • [63] Materials for fuel-cell technologies
    Steele, BCH
    Heinzel, A
    [J]. NATURE, 2001, 414 (6861) : 345 - 352
  • [64] Electrochemical Behavior of Pt Nanoparticles Supported on Meso- and Microporous Carbons for Fuel Cells
    Su, Fabing
    Poh, Chee Kok
    Tian, Zhigun
    Xu, Guangwen
    Koh, Guangyong
    Wang, Zhan
    Liu, Zhaolin
    Lin, Jianyi
    [J]. ENERGY & FUELS, 2010, 24 (07) : 3727 - 3732
  • [65] Ultrafine platinum nanoparticles uniformly dispersed on arrayed CNx nanotubes with high electrochemical activity
    Sun, CL
    Chen, LC
    Su, MC
    Hong, LS
    Chyan, O
    Hsu, CY
    Chen, KH
    Chang, TF
    Chang, L
    [J]. CHEMISTRY OF MATERIALS, 2005, 17 (14) : 3749 - 3753
  • [66] Supramaniam S., 1993, J ELECTROANAL CHEM, V357, P201
  • [67] Influence of boron on structure and oxidation behavior of graphite fiber, P120
    Howe, JY
    Jones, LE
    [J]. CARBON, 2004, 42 (03) : 461 - 467
  • [68] Electrocatalytic Activity of Nitrogen-Doped Carbon Nanotube Cups
    Tang, Yifan
    Allen, Brett L.
    Kauffman, Douglas R.
    Star, Alexander
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (37) : 13200 - 13201
  • [69] The role of low-energy electrons in focused electron beam induced deposition: four case studies of representative precursors
    Thorman, Rachel M.
    Kumar, Ragesh T. P.
    Fairbrother, D. Howard
    Ingolfsson, Oddur
    [J]. BEILSTEIN JOURNAL OF NANOTECHNOLOGY, 2015, 6 : 1904 - 1926
  • [70] Enhancement of the electroreduction of oxygen on Pt alloys with Fe, Ni, and Co
    Toda, T
    Igarashi, H
    Uchida, H
    Watanabe, M
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (10) : 3750 - 3756
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