Low-Temperature Chemical Vapor Deposition Synthesis of Pt-Co Alloyed Nanoparticles with Enhanced Oxygen Reduction Reaction Catalysis

被引:165
作者
Choi, Dong Sung [1 ]
Robertson, Alex W. [2 ]
Warner, Jamie H. [2 ]
Kim, Sang Ouk [1 ]
Kim, Heeyeon [3 ]
机构
[1] Korea Adv Inst Sci & Technol, Natl Creat Res Initiat Ctr Multidimens Directed N, Dept Mat Sci & Engn, 291 Daehak Ro, Daejeon 34141, South Korea
[2] Univ Oxford, Dept Mat, Parks Rd, Oxford OX1 3PH, England
[3] Korea Inst Energy Res, Energy Mat Lab, 152 Gajeong Ro, Daejeon 34129, South Korea
关键词
HIGH ELECTROCATALYTIC ACTIVITY; PARTICLE-SIZE; FUEL-CELLS; CARBON NANOTUBES; METAL NANOPARTICLES; SURFACE-COMPOSITION; SUPPORTED PLATINUM; ELECTROLYTE; GRAPHENE; NITROGEN;
D O I
10.1002/adma.201600469
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel Pt-Co alloyed nanocatalysts are generated via chemical vapor deposition-assisted facile one-pot synthesis. The method guarantees highly monodisperse Pt-Co alloy nanoparticles with precise control of metallic compositions within 1 at%. A significant features is that a perfectly alloyed single-crystal structure is obtained at temperatures as low as 500 degrees C, which is much lower than conventional alloying temperatures.
引用
收藏
页码:7115 / +
页数:9
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