Low-Temperature Chemical Vapor Deposition Synthesis of Pt-Co Alloyed Nanoparticles with Enhanced Oxygen Reduction Reaction Catalysis

被引:170
作者
Choi, Dong Sung [1 ]
Robertson, Alex W. [2 ]
Warner, Jamie H. [2 ]
Kim, Sang Ouk [1 ]
Kim, Heeyeon [3 ]
机构
[1] Korea Adv Inst Sci & Technol, Natl Creat Res Initiat Ctr Multidimens Directed N, Dept Mat Sci & Engn, 291 Daehak Ro, Daejeon 34141, South Korea
[2] Univ Oxford, Dept Mat, Parks Rd, Oxford OX1 3PH, England
[3] Korea Inst Energy Res, Energy Mat Lab, 152 Gajeong Ro, Daejeon 34129, South Korea
关键词
HIGH ELECTROCATALYTIC ACTIVITY; PARTICLE-SIZE; FUEL-CELLS; CARBON NANOTUBES; METAL NANOPARTICLES; SURFACE-COMPOSITION; SUPPORTED PLATINUM; ELECTROLYTE; GRAPHENE; NITROGEN;
D O I
10.1002/adma.201600469
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel Pt-Co alloyed nanocatalysts are generated via chemical vapor deposition-assisted facile one-pot synthesis. The method guarantees highly monodisperse Pt-Co alloy nanoparticles with precise control of metallic compositions within 1 at%. A significant features is that a perfectly alloyed single-crystal structure is obtained at temperatures as low as 500 degrees C, which is much lower than conventional alloying temperatures.
引用
收藏
页码:7115 / +
页数:9
相关论文
共 86 条
[1]  
[Anonymous], 2006, ANGEW CHEM-GER EDIT, DOI DOI 10.1002/ANGE.200504386
[2]   Formation of carbon-supported PtM alloys for low temperature fuel cells: a review [J].
Antolini, E .
MATERIALS CHEMISTRY AND PHYSICS, 2003, 78 (03) :563-573
[3]   Electrocatalysis of oxygen reduction on a carbon supported platinum-vanadium alloy in polymer electrolyte fuel cells [J].
Antolini, E ;
Passos, RR ;
Ticianelli, EA .
ELECTROCHIMICA ACTA, 2002, 48 (03) :263-270
[4]   Investigation of bimetallic Pt-M/C as DMFC cathode catalysts [J].
Baglio, V. ;
Stassi, A. ;
Di Blasi, A. ;
D'Urso, C. ;
Antonucci, V. ;
Arico, A. S. .
ELECTROCHIMICA ACTA, 2007, 53 (03) :1360-1364
[5]   Preparation of carbon-supported Pt-Pd electrocatalysts with improved physical properties using electroless deposition methods [J].
Beard, Kevin D. ;
Van Zee, J. W. ;
Monnier, John R. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2009, 88 (1-2) :185-193
[6]   Nanostructured Pt-alloy electrocatalysts for PEM fuel cell oxygen reduction reaction [J].
Bing, Yonghong ;
Liu, Hansan ;
Zhang, Lei ;
Ghosh, Dave ;
Zhang, Jiujun .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (06) :2184-2202
[7]   Graphene supported electrocatalysts for methanol oxidation [J].
Bong, Sungyool ;
Kim, Yang-Rae ;
Kim, In ;
Woo, Seunghee ;
Uhm, Sunghyun ;
Lee, Jaeyoung ;
Kim, Hasuck .
ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (01) :129-131
[8]   Binary and Ternary Doping of Nitrogen, Boron, and Phosphorus into Carbon for Enhancing Electrochemical Oxygen Reduction Activity [J].
Choi, Chang Hyuck ;
Park, Sung Hyeon ;
Woo, Seong Ihl .
ACS NANO, 2012, 6 (08) :7084-7091
[9]   Synthesis and Characterization of 9 nm Pt-Ni Octahedra with a Record High Activity of 3.3 A/mgPt for the Oxygen Reduction Reaction [J].
Choi, Sang-I ;
Xie, Shuifen ;
Shao, Minhua ;
Odell, Jonathan H. ;
Lu, Ning ;
Peng, Hsin-Chieh ;
Protsailo, Lesia ;
Guerrero, Sandra ;
Park, Jinho ;
Xia, Xiaohu ;
Wang, Jinguo ;
Kim, Moon J. ;
Xia, Younan .
NANO LETTERS, 2013, 13 (07) :3420-3425
[10]   Electrochemical templating of metal nanoparticles and nanowires on single-walled carbon nanotube networks [J].
Day, TM ;
Unwin, PR ;
Wilson, NR ;
Macpherson, JV .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (30) :10639-10647