Two new photoluminescent d10 coordination polymers constructed with carboxylates and 2-(5-(pyrazin-2-yl)-1H-1,2,4-triazol-3-yl)pyrazine generated in situ

被引：13

作者：

Peng, Meng-Xia ^{[1
,2
]}

Li, Cui-Jin ^{[1
]}

Tong, Ming-Liang ^{[1
]}

机构：

[1] Sun Yat Sen Univ, MOE Key Lab Bioinorgan & Synthet Chem, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China

[2] Jiaying Univ, Dept Chem, Meizhou 514015, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 06期

基金：

高等学校博士学科点专项科研基金; 中国国家自然科学基金;

关键词：

cadmium hydrothermal reaction; coordination polymer; photoluminescence 2-(5-(Pyrazin-2-yl)-1H-1,2,4-triazol-3yl)pyrazine;

D O I：

10.1016/j.inoche.2008.03.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrothermal reaction of Cd(OAc)(2)center dot 4H(2)O with 3,6-di(2-pyrazinyl)-1,4-dihydro-1,2,4,5-tetrazine (dpztzH(2)) at 165 degrees C resulted in the formation of a one-dimensional (1D) coordination polymer [Cd-3(OAc)(3)(dPZt)(3)]center dot 2H(2)O (1) (dpztH=2-(5-(pyrazin-2-yl)-1H-1,2,4-triazol-3-yl)pyrazine) and a new 3D microporous coordination network [Cd-2(2,4,6-pyta)(dpzt)(H2O)]center dot 2H(2)O (2) when pyridine-2,4,6-tricarboxylic acid (2,4,6-pytaH(3)) ligand was employed in the above reaction system, in which the anionic dpzt(-) ligand was resulted from the in situ solvothermal rearrangement and deamination of dpztzH(2). Both complexes emit strong photoluminescence. (c) 2008 Elsevier B.V. All rights reserved.

引用

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页码：707 / 710

页数：4

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