Preparation of carbon coated MoO2 nanobelts and their high performance as anode materials for lithium ion batteries

被引:146
作者
Yang, Lichun [1 ,2 ,3 ]
Liu, Lili [1 ,2 ]
Zhu, Yusong [1 ,2 ]
Wang, Xujiong [1 ,2 ]
Wu, Yuping [1 ,2 ]
机构
[1] Fudan Univ, Dept Chem, NEML, Shanghai 200433, Peoples R China
[2] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
[3] IFW Dresden, Inst Integrat Nanosci, D-01069 Dresden, Germany
关键词
STORAGE; INTERCALATION; REDUCTION; NANOWIRES; MECHANISM; NANORODS; CO3O4;
D O I
10.1039/c2jm31364b
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Carbon coated MoO2 nanobelts were successfully synthesized via a hydrothermal method followed by calcination under inert atmosphere, using alpha-MoO3 nanobelts as the precursor and self-template, ethanol as the reducer and glucose as the carbon source. Under the protection of polysaccharide resulting from glucose polycondensation, the 1-D morphology can be well retained during the reduction and carbonization processes. Tested as anode materials for lithium ion batteries, the carbon coated MoO2 nanobelts exhibit a reversible capacity of 769.3 mA h g(-1) at a current density of 100 mA g(-1) in the first cycle, and retain 80.2% of the capacity after 30 cycles. When the current density increases, this material shows high rate capability and good cycling performance.
引用
收藏
页码:13148 / 13152
页数:5
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