Fe doped Sb nanoparticles supported on heteroatoms co-doped carbon matrix as efficient electrocatalyst for hydrogen evolution reaction in both acid and alkaline media

被引：14
|
作者：
Cui, Min [1 ]
Wu, Zexing [2 ]
Li, Ping [3 ]
Xin, Liantao [2 ]
Wang, Shuai [1 ]
机构：
[1] Qilu Univ Technol, Sch Chem & Pharmaceut Engn, Shandong Prov Key Lab Mol Engn, Jinan 250353, Peoples R China
[2] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Shandong Key Lab Biochem Anal, State Key Lab Base Ecochem Engn, Qingdao 266042, Peoples R China
[3] Ocean Univ China, Sch Mat Sci & Engn, Qingdao 266042, Peoples R China
来源：
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS | 2020年 / 110卷
基金：
中国国家自然科学基金;
关键词：
Electrocatalysts; Hydrogen evolution reaction; Sb nanoparticles; Carbon matrix; HIGH-PERFORMANCE ANODE; HIGHLY EFFICIENT; NITROGEN; GRAPHENE; CATALYST; NANOSTRUCTURES; PHOSPHIDES; NANOSHEETS; COMPOSITE; ARRAY;
D O I：
10.1016/j.jtice.2020.03.012
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Exploring non-precious, efficient and earth abundant electrocatalysts plays significant role on the large-scale applications of sustainable hydrogen energy. Herein, a facile and scalable strategy is developed to prepare Fe doped Sb nanoparticles supported on heteroatoms (N, P and 5) co-doped carbon matrix (Fe-Sb/NPSC). Electrochemical measurements results demonstrated that the obtained electrocatalyst possesses excellent catalytic activities for hydrogen evolution reaction (HER) in both acid (174 mV@10 mA cm(-2)) and alkaline (242 mV@10 mA cm(-2)) media. Moreover, the obtained electrocatalyst also owns excellent long-term stability. This work paves a facile avenue to develop Sb based electrocatalysts for HER and other related energy conversion technologies. (C) 2020 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：51 / 57
页数：7
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