Glycosylation of acid sensitive acceptors. Synthesis of (2,3-epoxy-1-propyl) glycosides

被引：3
|
作者：
Kasprzycka, A
Szeja, W
Grynkiewicz, G
机构：
[1] Silesian Tech Univ, Dept Chem, PL-44100 Gliwice, Poland
[2] Pharmaceut Res Inst, PL-01793 Warsaw, Poland
来源：
CARBOHYDRATE RESEARCH | 2005年 / 340卷 / 15期
关键词：
glycidyl glycosides; glycosides; glycosylation; N-allyl thiocarbamates;
D O I：
10.1016/j.carres.2005.07.010
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Treatment of O-benzylated derivatives of glycosyl N-allyl thiocarbamate with racemic or enantiomerically pure glycidol and bromine provides the 1,2-cis-glycidyl glycosides. This protocol was mild, highly stereoselective and efficient. (C) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2443 / 2446
页数：4
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