Gallium-boron donor-acceptor bonds

被引：86

作者：

Hardman, NJ

Power, PP ^{[1
]}

Gorden, JD

Macdonald, CLB

Cowley, AH

机构：

[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA

[2] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 18期

关键词：

D O I：

10.1039/b106599h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Examples of compounds with gallium-boron donor-acceptor bonds, HC[MeC(2,6-(Pr2C6H3)-C-i)N](2)Ga-->B(C6F5)(3) 3 and (eta (5)-C5Me5)Ga--->B(C6F5)(3) 4 have been prepared by treatment of the free gallanediyls with B(C6F5)(3); the structures of both compounds were determined by X-ray crystallography.

引用

收藏

页码：1866 / 1867

页数：2

相关论文

共 18 条

[1] A Lewis acid adduct of an alanediyl: An aluminum(I)-boron donor-acceptor bond [J].

Gorden, JD ;

Voigt, A ;

Macdonald, CLB ;

Silverman, JS ;

Cowley, AH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (05) :950-951

[2] THE MOLECULAR-STRUCTURE OF PENTAMETHYLCYCLOPENTADIENYLGALLIUM, GA(ETA-C5ME5), BY GAS-PHASE ELECTRON-DIFFRACTION - THE 1ST MONOMERIC ORGANOGALLIUM(I) COMPOUND [J].

HAALAND, A ;

MARTINSEN, KG ;

VOLDEN, HV ;

LOOS, D ;

SCHNOCKEL, H .

ACTA CHEMICA SCANDINAVICA, 1994, 48 (02) :172-174

[3] MOLECULAR-STRUCTURE OF MONOMERIC (PENTAMETHYLCYCLOPENTADIENYL)ALUMINUM(I) BY GAS-PHASE ELECTRON-DIFFRACTION [J].

HAALAND, A ;

MARTINSEN, KG ;

SHLYKOV, SA ;

VOLDEN, HV ;

DOHMEIER, C ;

SCHNOCKEL, H .

ORGANOMETALLICS, 1995, 14 (06) :3116-3119

[4] Synthesis and characterization of the monomer Ga{(NDippCMe)2CH} (Dipp = C6H3Pri2-2,6):: a low valent gallium(I) carbene analogue [J].

Hardman, NJ ;

Eichler, BE ;

Power, PP .

CHEMICAL COMMUNICATIONS, 2000, (20) :1991-1992

[5]

HARDMAN NJ, UNPUB

[6] Chemistry of C-trimethylsilyl-substituted heterocarboranes .22. Synthetic, spectroscopic, structural, and bonding studies on half- and full-sandwich gallacarboranes of 2,3- and 2,4-C2B4 carborane ligand systems [J].

Hosmane, NS ;

Lu, KJ ;

Zhang, HM ;

Maguire, JA .

ORGANOMETALLICS, 1997, 16 (24) :5163-5170

[7] Lewis acid properties of tris(pentafluorophenyl)borane.: Structure and bonding in L-B(C6F5)3 complexes [J].

Jacobsen, H ;

Berke, H ;

Döring, S ;

Kehr, G ;

Erker, G ;

Fröhlich, R ;

Meyer, O .

ORGANOMETALLICS, 1999, 18 (09) :1724-1735

[8] Cp* Chemistry of main-group elements [J].

Jutzi, P ;

Reumann, G .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (14) :2237-2244

[9] Lewis acid-base adducts of pentamethylcyclopentadienylgallium with trivalent group 13-element compounds [J].

Jutzi, P ;

Neumann, B ;

Reumann, G ;

Schebaum, LO ;

Stammler, HG .

ORGANOMETALLICS, 2001, 20 (13) :2854-2858

[10] Synthesis and structure of a tetragallane [R4Ga4I3]- and a polyhedral nonagallane [R6Ga9]- [J].

Köstler, W ;

Linti, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (23) :2644-2646