Lithium-ion rechargeable battery with petroleum coke anode and polyaniline cathode

被引:21
|
作者
Qiu, WH
Zhou, RQ
Yang, LL
Liu, QG
机构
[1] University of Science and Technology
[2] Res. Institute of Chemical Industry
关键词
lithium-ion battery; polyaniline cathode; petroleum coke anode;
D O I
10.1016/0167-2738(96)00211-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper, a study on the lithium-ion rechargeable battery based on a petroleum coke anode and a polyaniline cathode is introduced. The new battery is different from other Lithium-ion rechargeable batteries in which transition metal oxides are used as the cathode materials. During the charging, Li+ cations are intercalated in carbon layers and ClO4- anions are simultaneously doped on the aniline chain. During discharging, both Li+ and ClO4- are removed to the electrolyte solution from the anode and cathode, respectively. This battery avoids safety and poor rechargeability problems because there is no dendrite growth and no changes in morphology. Therefore, the new battery possesses good rechargeable and reversible characteristics.
引用
收藏
页码:903 / 906
页数:4
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