An inexpensive and simple process for the preparation of antimony(III) and bismuth(III) triflates

被引:37
|
作者
Peyronneau, M
Arrondo, C
Vendier, L
Roques, N
Le Roux, C
机构
[1] Univ Toulouse 3, Dept Chem, Lab Heterochim Fondamentale & Appl, CNRS,UMR 5069, F-31062 Toulouse 04, France
[2] CNRS, UPR 8011, Ctr Elaborat Mat & Etud Struct, F-31055 Toulouse, France
[3] Ctr Rech Lyon, Rhodia Organ Fine, F-69192 St Fons, France
关键词
antimony; bismuth; triflate; catalysts; organic synthesis;
D O I
10.1016/j.molcata.2003.10.020
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new process for the preparation of antimony and bismuth(III) triflates has been found. This process is based on the reaction of triflic acid on metal oxide using chlorobenzene as a solvent. Due to its simplicity, this process can be useful for the laboratory scale as well as the industrial preparation of these metal triflates. (C) 2003 Elsevier B.V. All rights reserved.
引用
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页码:89 / 91
页数:3
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