Cobalt-rhodium heterobimetallic nanoparticle-catalyzed reactions

被引：32
|
作者：
Park, Ji Hoon
Chung, Young Keun [1 ]
机构：
[1] Seoul Natl Univ, Intelligent Textile Syst Res Ctr, Seoul 151747, South Korea
来源：
DALTON TRANSACTIONS | 2008年 / 18期
关键词：
D O I：
10.1039/b718609f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Transition metal nanoparticles have attracted a great deal of attention. This review discusses the synthesis of heterobimetallic cobalt-rhodium nanoparticles and their use as catalysts in organic transformations. Co-Rh nanoparticles (Co2Rh2) with a fixed stoichiometry (2 : 2) were easily obtained from Co2Rh2(CO)(12). These nanoparticles were quite effective catalysts for carbonylation reactions. Particularly, special focus is paid to the Pauson-Khand-type reaction.
引用
收藏
页码：2369 / 2378
页数：10
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