Synthesis of α-sulfonyloxyketones via iodobenzene diacetate (PIDA)-mediated oxysulfonyloxylation of alkynes with sulfonic acids

被引：5
|
作者：
Zhang, Yang [1 ]
Tan, Hua [1 ]
Liu, Weibing [1 ]
机构：
[1] Guangdong Univ Petrochem Technol, Coll Chem Engn, 2 Guandu Rd, Maoming 525000, Peoples R China
来源：
RSC ADVANCES | 2017年 / 7卷 / 85期
关键词：
HYPERVALENT IODINE REAGENT; TOSYLOXY KETONES; PHASE;
D O I：
10.1039/c7ra11875a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A simple yet powerful method to synthesize a variety of a-sulfonyloxyketones has been developed. This novel method can be applied for the direct oxysulfonyloxylation of alkynes with sulfonic acids to access a variety of alpha-sulfonyloxyketones. Compared to the reported methods for the application of PIDA, this study expands its application scope and uses it not only as the oxidant but also as the carrier of "O" to form the carbonyl group in the products. In addition, under the established conditions, this methodology not only exhibits a broad substrate scope but also demonstrates exclusive regioselectivity with substrates of 1,2-disubstituted internal alkynes.
引用
收藏
页码：54017 / 54020
页数：4
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