Pd-EDTA as an efficient catalyst for Suzuki-Miyaura reactions in water

被引：61

作者：

Korolev, DN ^{[1
]}

Bumagin, NA ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 34期

关键词：

Suzuki-Miyaura reaction; palladium; EDTA; biaryls; catalysis;

D O I：

10.1016/j.tetlet.2005.06.085

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

PdCl2-EDTA complex I is an efficient catalyst for the Suzuki-Miyaura reactions of aryl and heteroaryl halides with aryl(heteroaryl)boronic acids in water at 20-100 degrees C. Aryl iodides and bromides undergo the cross-coupling with turnover numbers (TON) up to 97,000 and turnover frequencies (TOF) up to 582,000 h(-1). (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：5751 / 5754

页数：4

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