Solvent-induced control of ultrasonic deuterium labelling

被引：18
作者：
Cioffi, EA
机构：
[1] Department of Chemistry, Univ. of Rhode Island, Kingston
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 35期
关键词：
D O I：
10.1016/0040-4039(96)01345-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Raney Nickel catalyzed hydrogen-deuterium exchange in a model monosaccharide was conducted in eight different solvent pairs under ultrasonic irradiation. Immiscible solvent pairs gave percentages of stereospecific deuterium incorporation comparable to those reported previously; pronounced regioselectivity was demonstrated in two of the pairs examined. Copyright (C) 1996 Elsevier Science Ltd
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页码：6231 / 6234
页数：4
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