Arynes in Transition-Metal-Free Multicomponent Coupling Reactions

被引：170

作者：

Bhojgude, Sachin Suresh ^{[1
]}

Biju, Akkattu T. ^{[1
]}

机构：

[1] CSIR NCL, Div Organ Chem, Pune 411008, Maharashtra, India

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 07期

关键词：

arenes; arynes; isocyanides; multicomponent reactions; synthetic methods; STRAIGHTFORWARD ACCESS; SIGMA-BONDS; INSERTION; BENZYNE; ISOCYANIDES;

D O I：

10.1002/anie.201106984

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Let's couple together! The multicomponent reactions involving arynes offer direct access to unusual heterocyclic scaffolds and 1,2-disubstituted arenes. This transition-metal-free, one-pot construction of molecular complexity is likely to play a pivotal role in various carbon-carbon and carbon-heteroatom bond-forming reactions. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1520 / 1522

页数：3

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