Microbial fuel cell using ferrous ion activated persulfate as a cathodic reactant

被引:22
作者
Wang, Ying [1 ,2 ]
Niu, Cheng-Gang [1 ,2 ]
Zeng, Guang-Ming [1 ,2 ]
Hu, Wen-Juan [1 ,2 ]
Huang, Da-Wei [1 ,2 ]
Ruan, Min [1 ,2 ]
机构
[1] Hunan Univ, Coll Environm Sci & Engn, Changsha 410082, Hunan, Peoples R China
[2] Hunan Univ, Minist Educ, Key Lab Environm Biol & Pollut Control, Changsha 410082, Hunan, Peoples R China
基金
中国国家自然科学基金; 高等学校博士学科点专项科研基金;
关键词
Microbial fuel cell; Ferrous ion activated persulfate; Cathodic reactant; Maximum power density; ELECTRICITY-GENERATION; PERFORMANCE; AIR; CHALLENGES; OXIDATION; PH;
D O I
10.1016/j.ijhydene.2011.08.071
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the present paper, the K2S2O8-Fe2+ system without pH adjustment was used as a cathodic reactant in a two-chamber microbial fuel cell (MFC) for the first time. The performance of the MFC with K2S2O8-Fe2+ system was discussed and compared with that of K2S2O8 and H2O2-Fe2+ system, respectively. These results demonstrated that the introduced ferrous ion could improve the power generation significantly. The initial K2S2O8/Fe2+ molar ratios and the pH, which can affect the performance of MFC, were discussed later. The results revealed that K2S2O8-Fe2+ system achieved the best performance at K2S2O8/Fe2+ molar ratios of 2:1 and the K2S2O8-Fe2+ system was stable with varying pH value. This study demonstrated that the K2S2O8-Fe2+ system can be used as an effective cathodic reactant due to its excellent performance. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:15344 / 15351
页数:8
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