Magmatic evolution of the differentiated ultramafic, alkaline and carbonatite intrusion of vuoriyarvi (Kola Peninsula, Russia). A LA-ICP-MS study of apatite

被引:55
作者
Brassinnes, S
Balaganskaya, E
Demaiffe, D
机构
[1] Univ Libre Bruxelles, B-1050 Brussels, Belgium
[2] RAS, Kola Sci Ctr, Inst Geol, Apatity 184209, Russia
关键词
carbonatite; Kola; apatite; LA-ICP-MS; fractional crystallisation;
D O I
10.1016/j.lithos.2005.03.017
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
The nature of the petrogenetic links between carbonatites and associated silicate rocks is still under discussion (i.e., [Gittins J., Harmer R.E., 2003. Myth and reality of the carbonatite-silicate rock "association". Period di Mineral. 72, 19-26]). In the Paleozoic Kola alkaline province (NW Russia), the carbonatites are spatially and temporally associated to ultramafic cumulates (clinopyroxenite, wehrlite and dunite) and alkaline silicate rocks of the ijolite-melteigite series [Kogarko, L.N., 1987. Alkaline rocks of the eastern part of the Baltic Shield (Kola Peninsula). In: Fitton, J.G., and Upton, B.G.J. (eds). Alkaline igneous rocks. Geol. Soc. Special Publication 30, 531-544; Kogarko, L.N., Kononova, V.A., Orlova, M.P., Woolley, A.R., 1995. Alkaline rocks and carbonatites of the world. Part 2. Former USSR. Chapman and Hall, London, 225 pp; Verhulst, A., Balaganskya, E., Kimarsky, Y., Demaiffe, D., 2000. Petrological and geochemical (trace elements and Sr-Nd isotopes) characteristics of the Paleozoic Kovdor ultramafic, alkaline and carbonatite intrusion (Kola Peninsula, NW Russia). Lithos 51, 1-25; Dunworth, E.A., Bell, K., 2001. The Turiy Massif, Kola Peninsula, Russia; isotopic and geochemical evidence for a multi-source evolution. J. Petrol. 42, 377-405; Woolley, A.R., 2003. Igneous silicate rocks associated with carbonatites: their diversity, relative abundances and implications for carbonatite genesis. Period. di Mineral. 72, 9-17)]. In the small (approximate to 20 km(2)) Vuoriyarvi massif, apatite is typically a liquidus phase during the magmatic evolution and so it can be used to test genetic relationships. Trace elements contents have been obtained for both whole rocks and apatite (by LA-ICP-MS). The apatites define a single continuous chemical evolution marked by an increase in REE and Na (belovite-type of substitution, i.e., 2Ca(2+) = Na+ + REE3+). This evolution possibly reflects a fractional crystallisation process of a single batch of isotopically homogeneous, mantle-derived magma. The distribution of REE between apatite and their host carbonatite have been estimated from the apatite composition of a carbonatite vein, belonging to the Neskevara conical-ring-like vein system. This carbonatite vein is tentatively interpreted as a melt. So, the calculated distribution coefficients are close to partition coefficients. Rare earth elements are compatible in apatite (D > 1) with a higher compatibility for the middle REE (D-Sm,: 6. 1) than for the light (D-La: 4. 1) and the heavy (D-Yb: 1) REE. (c) 2005 Elsevier B.V. All rights reserved.
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页码:76 / 92
页数:17
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