Large-ring Cyclodextrins

被引:20
作者
Endo, Tomohiro [1 ]
机构
[1] Hoshi Univ, Dept Funct Radiat Sci, Shinagawa Ku, Tokyo 1428501, Japan
关键词
cyclodextrin; large-ring cyclodextrin; physicochemical property; inclusion complex formation ability; production; CYCLOMALTONONAOSE DELTA-CYCLODEXTRIN; X-RAY-STRUCTURE; CYCLOMALTODECAOSE EPSILON-CYCLODEXTRIN; GLYCOGEN DEBRANCHING ENZYME; INCLUSION COMPLEX-FORMATION; POTATO D-ENZYME; GAMMA-CYCLODEXTRIN; ATOMIC-RESOLUTION; AQUEOUS-SOLUTION; PHYSICOCHEMICAL PROPERTIES;
D O I
10.4052/tigg.23.79
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Cyclodextrin (CD) is the common name for cyclic alpha-1,4-glucans; alpha-, beta- and gamma-CD, which are composed of 6, 7, 8 D-glucopyranose units, are well-known. However, most scientists have not recognized large-ring cyclodextrins (LR-CDs) composed of more than 9 D-glucopyranose units until recently, although the existence of LR-CDs containing 9-13 D-glucopyranose units in macrocycle was reported about a half century ago. The characteristics of LR-CDs have been studied for the last quarter century, and they are still relatively new materials. In this minireview, the unique characteristics of LR-CDs, including molecular structure, physicochemical properties and inclusion complex formation ability, are discussed. Preparation and purification methods are also reviewed.
引用
收藏
页码:79 / 92
页数:14
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