Formation of a double salt and mixed crystals in the Ca(HCOO)2-Cd(HCOO)2-H2O system

被引：4
|
作者：
Vassileva, VZ [1 ]
机构：
[1] Bulgarian Acad Sci, Inst Gen & Inorgan Chem, BU-1113 Sofia, Bulgaria
来源：
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 1998年 / 63卷 / 12期
关键词：
solubility diagrams; calcium/cadmium formate double salt; calcium/cadmium formats mixed crystals; calcium; cadmium;
D O I：
10.1135/cccc19982036
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
By solubility method in the Ca(HCOO)(2)-Cd(HCOO)(2)-H2O system at 25 and 50 degrees C, the formation of a double salt CaCd(HCOO)(4) and mixed crystals Ca1-xCdx(HCOO)(2) was established. The double salt formation is explained by the electronic configuration of the metal ions involved. Formation of the mixed crystals, possessing the alpha-Ca(HCOO)(2) structure, is attributed to the ability of the Cd2+ ions to accept the coordination environment, characteristic of the Ca2+ ions in alpha-Ca(HCOO)(2).
引用
收藏
页码：2036 / 2043
页数：8
相关论文
共 50 条
  • [41] Solubility in the Sr(HCOO)(2)-Ni(HCOO)(2)-H2O system at 25 degrees C
    Fakeev, AA
    Akhtamova, AS
    Iskhakova, LD
    Konkova, OV
    Zhadanov, BV
    ZHURNAL NEORGANICHESKOI KHIMII, 1996, 41 (04): : 702 - 704
  • [42] THE FORMATION OF NEW PHASES IN THE CD(HCOO)2-LI(NAK,NH4)HCOO-H2O SYSTEMS
    ITKINA, LS
    NADZHARYAN, KA
    ZHURNAL NEORGANICHESKOI KHIMII, 1981, 26 (08): : 2231 - 2234
  • [43] 25 degrees C solubility behavior in the Sr(HCOO)(2)-Mn(HCOO)(2)-H2O system
    Fakeev, AA
    Akhtamova, AS
    Konkova, OV
    Iskhakova, LD
    Zhadanov, BV
    ZHURNAL NEORGANICHESKOI KHIMII, 1997, 42 (05): : 814 - 817
  • [44] The Ca(HCOO)(2)-Mn(HSOO)(2)-H2O system at 25 degrees C
    Fakeev, AA
    Orlova, IV
    Zhadanov, BV
    ZHURNAL NEORGANICHESKOI KHIMII, 1996, 41 (08): : 1379 - 1381
  • [45] New ferroelastics Lu(HCOO)3 • 2H2O and Tm(HCOO)3 • 2H2O
    Kirpichnikova, LF
    Hilczer, B
    Kulek, J
    Soboleva, LV
    Polomska, M
    Shuvalov, LA
    CRYSTALLOGRAPHY REPORTS, 1999, 44 (06) : 1042 - 1044
  • [46] CD(HCOO)2-HCOOH-H2O SYSTEM AT 50-DEGREE-C
    CHAPLYGINA, NM
    PORTNOVA, SM
    ZHURNAL NEORGANICHESKOI KHIMII, 1985, 30 (08): : 2178 - 2180
  • [47] Solubility in the system 2HCOONa+CaCl2 ⇆ (HCOO)2Ca+2NaCl-H2O
    Gordenchuk, A. D.
    Kudryashova, O. S.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2017, 62 (08) : 1099 - 1103
  • [48] POLYMORPHIC TRANSFORMATIONS OF TH (HCOO)4 AND CA(HCOO)2
    MENTZEN, B
    BULLETIN DE LA SOCIETE FRANCAISE MINERALOGIE ET DE CRISTALLOGRAPHIE, 1971, 94 (02): : 138 - &
  • [49] Formation of copper-manganese oxides from CuxMn1-x(HCOO)2•2H2O mixed crystals
    Koleva, V
    Stoilova, D
    Mehandjiev, D
    JOURNAL OF SOLID STATE CHEMISTRY, 1997, 133 (02) : 416 - 422
  • [50] Thermal and electrical studies on mixed crystals of CuxZn1−x(HCOO)2·2H2O
    M. G. El-Shaarawy
    S. A. Shama
    Journal of Materials Science, 1999, 34 : 1229 - 1232
12345