Copper(II)-Catalyzed Oxidative Coupling of Anilines, Methyl Arenes, and TMSN3 via C(sp3/sp2)-H Functionalization and C-N Bond Formation

被引：30

作者：

Mahesh, Devulapally ^{[1
]}

Satheesh, Vanaparthi ^{[1
]}

Kumar, Sundaravel Vivek ^{[1
]}

Punniyamurthy, Tharmalingam ^{[1
]}

机构：

[1] Indian Inst Technol Guwahati, Dept Chem, Gauhati 781039, India

来源：

ORGANIC LETTERS | 2017年 / 19卷 / 24期

关键词：

H AMINATION; SULFONYL AZIDES; CATALYZED AMIDATION; ROOM-TEMPERATURE; MILD CONDITIONS; ONE-POT; BENZIMIDAZOLES; DERIVATIVES; MOLECULES; KETONES;

D O I：

10.1021/acs.orglett.7b03264

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Copper(II)-catalyzed cross-coupling of anilines, methyl arenes, and TMSN3 in the presence of tertbutylhydroperoxide at moderate temperature produced 2-aryl benzimidazoles via a tandem C(sp(3)/sp(2))-H functionalization and C-N bond formations. The selectivity and multiple C-H functionalization of the simple substrates are significant practical features.

引用

页码：6554 / 6557

页数：4

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