Thermo-Switchable Materials Prepared Using the OEGMA-Platform

被引：367

作者：

Lutz, Jean-Francois ^{[1
]}

机构：

[1] CNRS, Inst Charles Sadron, UPR22, F-67034 Strasbourg 2, France

来源：

ADVANCED MATERIALS | 2011年 / 23卷 / 19期

关键词：

TRANSFER RADICAL POLYMERIZATION; STIMULI-RESPONSIVE POLYMER; OLIGO(ETHYLENE GLYCOL) METHACRYLATE; HAIRY HYBRID NANOPARTICLES; IN-SITU GROWTH; DIBLOCK COPOLYMERS; AQUEOUS-SOLUTIONS; CELL-ADHESION; 2-(2-METHOXYETHOXY)ETHYL METHACRYLATE; TUNABLE THERMOSENSITIVITY;

D O I：

10.1002/adma.201100597

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We describe here the advantages of oligo(ethylene glycol)-based (co)polymers for preparing thermoresponsive materials as diverse as polymer-enzyme bio-hybrids, injectable hydrogels, capsules for drug-release, modified magnetic particles for in vivo utilization, cell-culture substrates, antibacterial surfaces, or stationary phases for bioseparation. Oligo(ethylene glycol) methacrylates (OEGMAs) can be (co)polymerized using versatile and widely-applicable methods of polymerization such as atom transfer radical polymerization (ATRP) of reversible addition-fragmentation chain-transfer (RAFT) polymerization. Thus, the molecular structure and therefore the stimuli-responsive properties of these polymers can be precisely controlled. Moreover, these stimuli-responsive macromolecules can be easily attached to or directly grown from organic, inorganic or biological materials. As a consequence, the OEGMA synthetic platform is today a popular option for materials design. The present research news summaries the progress of the last two years.

引用

页码：2237 / 2243

页数：7

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