Synthesis of enantiomerically pure cycloalkenols via combination strategy of enzyme-catalyzed reaction and RCM reaction

被引：17

作者：

Shi-Hui, Han ^{[1
]}

Hirakawa, Takuya ^{[1
]}

Fukuba, Takaaki ^{[1
]}

Hayase, Shuichi ^{[1
]}

Kawatsura, Motoi ^{[1
]}

Itoh, Toshiyuki ^{[1
]}

机构：

[1] Tottori Univ, Fac Engn, Dept Mat Sci, Tottori 6808552, Japan

来源：

TETRAHEDRON-ASYMMETRY | 2007年 / 18卷 / 20期

关键词：

D O I：

10.1016/j.tetasy.2007.10.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of three types of cyclic alkenols, (S)-2-cyclohexenol, (R)-2,5-dihydrobenzo[b]oxepin-5-ol, and (R)-5,6-dihydro-2H- benzo[b]oxocin-6-ol, has been accomplished in enantiomerically pure forms as model compounds using a combination of a lipase-catalyzed reaction and a ring closing olefin metathesis (RCM) reaction. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：2484 / 2490

页数：7

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