A novel copper (II) metallacycle as a building block for the assembly of an extended supramolecular array containing channels and helical chains

被引：9

作者：

Cooper, GJT ^{[1
]}

Long, DL ^{[1
]}

Cronin, L ^{[1
]}

机构：

[1] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 08期

关键词：

supramolecular; coordination chemistry; metallacycles; hydrogen bonding; rigid aliphatic ligands; metal organic frameworks; self assembly;

D O I：

10.1016/j.inoche.2005.05.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexation of copper (II) perchlorate with cis, cis-1,3,5-cyclohexanetricarboxylic acid (CTA) and cis, trans-1,3,5-triaminocyclohexane (trans-tach) in the presence of triethylamine leads to the formation of a dinuclear metallacycle; [Cu-2(trans-tach)2 (CTA)(2)] center dot 14H(2)O (1). The crystal structure of 1 shows an extended hydrogen bonded network comprising linear chains of metallacycles running perpendicular to solvent occupied channels. (C) 2005 Elsevier B.V. All rights reserved.

引用

页码：737 / 739

页数：3

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