[μ-Bis(diphenylphosphanyl)methane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[tris(biphenyl-4-yl)arsane-3κAs]-triangulo-triruthenium(0)

被引：1
作者：
bin Shawkataly, Omar [1 ]
Khan, Imthyaz Ahmed [1 ]
Sirat, Siti Syaida [1 ]
Yeap, Chin Sing [2 ]
Fun, Hoong-Kun [2 ]
机构：
[1] Univ Sains Malaysia, Sch Distance Educ, Chem Sci Programme, Usm 11800, Penang, Malaysia
[2] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, Usm 11800, Penang, Malaysia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
LIGAND-SUBSTITUTED DERIVATIVES; X-RAY STRUCTURES; CLUSTER CHEMISTRY; STEREOCHEMISTRY; P(OCH2CF3)3; COMPLEXES; PPH(OME)2; RU3(CO)12; OS3(CO)12;
D O I：
10.1107/S160053681100078X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title triangulo-triruthenium compound, [Ru-3(C36H27As)(C25H22P2)(CO)(9)], the bis(diphenylphosphanyl)methane ligand bridges an Ru-Ru bond and the monodentate arsine ligand bonds to the third Ru atom. Both the arsine and phosphine ligands are equatorial with respect to the Ru-3 triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. In each biphenyl unit, the phenyl rings are twisted from each other, making dihedral angles of 51.22 (18), 42.94 (16) and 26.95 (16)degrees. The arsine-substituted phenyl rings make dihedral angles of 61.22 (15), 87.17 (15) and 83.32 (15)degrees with each other. The dihedral angles between the two benzene rings are 85.52 (18) and 81.77 (15)degrees for the two diphenylphosphanyl groups, respectively. In the crystal, molecules are linked into dimers by intermolecular C-H center dot center dot center dot O hydrogen bonds. Weak intermolecular C-H center dot center dot center dot pi and pi-pi [centroid-centroid distance = 3.6981 (18) angstrom] interactions stabilize the crystal structure.
引用
收藏
页码：M216 / U1001
页数：20
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