Porphyrin-based two-dimensional covalent organic frameworks: synchronized synthetic control of macroscopic structures and pore parameters

被引：212

作者：

Feng, Xiao ^{[1
,2
]}

Chen, Long ^{[1
]}

Dong, Yuping ^{[2
]}

Jiang, Donglin ^{[1
,3
]}

机构：

[1] Natl Inst Nat Sci, Dept Mat Mol Sci, Inst Mol Sci, Okazaki, Aichi 4448787, Japan

[2] Beijing Inst Technol, Coll Mat Sci & Engn, Beijing 100081, Peoples R China

[3] Japan Sci & Technol Agcy JST, Precursory Res Embryon Sci & Technol PRESTO, Tokyo, Japan

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 07期

关键词：

HYDROGEN STORAGE MATERIALS; RETICULAR SYNTHESIS; CRYSTALLINE; GENERATION;

D O I：

10.1039/c0cc04386a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A two-dimensional porphyrin covalent organic framework is solvothermally synthesized and the macroscopic structure and pore parameters can be synthetically controlled. A remarkable and positive COF size effect on the pore parameters enables such structural control with a synchronized feature.

引用

页码：1979 / 1981

页数：3

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