Syntheses, Crystal Structures, and Spectral Properties of Two Coordination Compounds Based on 1,2-Bis(benzimidazolyl)benzene

被引：1

作者：

Meng, Fa-Yan ^{[1
]}

Jiang, Bing-Li ^{[1
]}

Lin, Cui-Wu ^{[1
]}

Wang, Li ^{[1
]}

Tan, Xiao-He ^{[1
]}

机构：

[1] Guangxi Univ, Coll Chem & Chem Engn, Nanning 530004, Guangxi, Peoples R China

来源：

BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2011年 / 32卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Copper (II); 1,2-Bis(benzimidazolyl)benzene; Dicarboxylate; Crystal structures; Spectral properties; METAL-ORGANIC FRAMEWORKS; ZEOLITIC IMIDAZOLATE FRAMEWORKS; CARBON-DIOXIDE; BUILDING UNITS; COMPLEXES; POLYMERS; NETWORK; LIGAND; PHOTOLUMINESCENCE; ADSORPTION;

D O I：

10.5012/bkcs.2011.32.3.1017

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two new benzimidazolyl-containing complexes have been synthesized by reactions of Cu-II salts and 1,2-bis(benzimidazolyl)benzene (H(2)bbbz) with two different dicarboxylate ligands. When phthalate acid (H(2)pt) was employed as secondary ligand, a 0D molecular complex Cu(H(2)bbbz)(pt)center dot(H(2)pt) (1) was furnished and when the secondary ligand was instead by a linear bridging ligand of terephthalic acid (H(2)tp) a 1D zipper-like coordination polymer [Cu(H(2)bbbz)(tp)center dot 2(C2H5OH)center dot H2O](n) (2) was obtained, suggesting the structure-direction effect of the secondary dicarbxylate ligand. The preliminary investigation on the spectral properties of the complexes was also presented.

引用

页码：1017 / 1021

页数：5

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