Size control by rate control in colloidal PbSe quantum dot synthesis

被引：26

作者：

Capek, Richard Karel ^{[1
]}

Yanover, Dianna ^{[1
]}

Lifshitz, Efrat ^{[1
]}

机构：

[1] Technion Israel Inst Technol, Inst Solid State, Russell Berrie Nanotechnol Inst, Schulich Fac Chem, IL-32000 Haifa, Israel

来源：

NANOSCALE | 2015年 / 7卷 / 12期

关键词：

SEMICONDUCTOR NANOCRYSTAL SYNTHESIS; II-VI; EXTINCTION COEFFICIENT; SELENIDE; REACTIVITY; GROWTH; CDS;

D O I：

10.1039/c5nr00028a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A recently demonstrated approach to control the size of colloidal nanoparticles, "size control by rate control", which was validated on the examples of colloidal CdSe-and CdS-quantum dot (CQD) synthesis, appears to be a general strategy for designing technically applicable CQD-syntheses. The "size control by rate control" concept allows full-yield syntheses of ensembles of CQDs with different sizes by tuning the solute formation rate. In this work, we extended this strategy to dialkylphosphine enhanced hot-injection synthesis of PbSe-CQDs. Furthermore, we provide new insight into the reaction mechanism of dialkylphosphine enhancement in TOPSe based CQD-syntheses.

引用

页码：5299 / 5310

页数：12

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