Perovskite oxynitrides as tunable materials for electrocatalytic nitrogen reduction to ammonia

被引：6
作者：
Young, Samuel D. [1 ,2 ]
Banerjee, Amitava [2 ]
Pilania, Ghanshyam [2 ]
Goldsmith, Bryan R. [1 ]
机构：
[1] Univ Michigan, Dept Chem Engn, 2300 Hayward St, Ann Arbor, MI 48109 USA
[2] Los Alamos Natl Lab, POB 1663, Los Alamos, NM 87545 USA
来源：
TRENDS IN CHEMISTRY | 2021年 / 3卷 / 09期
关键词：
CATALYSTS; VANADIUM;
D O I：
10.1016/j.trechm.2021.07.002
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The electrocatalytic nitrogen reduction reaction (ENRR) to ammonia is a potentially sustainable alternative to the Haber-Bosch (HB) process, but low Faradaic efficiencies and rates hinder its implementation. Perovskite oxynitrides are a tunable class of materials with unique chemistry for ENRR. Elucidating structure-property-mechanism relations for perovskite oxynitrides will aid ENRR catalyst design.
引用
收藏
页码：694 / 696
页数：3
相关论文
共 14 条
  • [1] Roads less traveled: Nitrogen reduction reaction catalyst design strategies for improved selectivity
    Ceballos, Bianca M.
    Pilania, Ghanshyam
    Ramaiyan, Kannan P.
    Banerjee, Amitava
    Kreller, Cortney
    Mukundan, Rangachary
    [J]. CURRENT OPINION IN ELECTROCHEMISTRY, 2021, 28 (28)
  • [2] Catalysts for nitrogen reduction to ammonia
    Foster, Shelby L.
    Bakovic, Sergio I. Perez
    Duda, Royce D.
    Maheshwari, Sharad
    Milton, Ross D.
    Minteer, Shelley D.
    Janik, Michael J.
    Renner, Julie N.
    Greenlee, Lauren F.
    [J]. NATURE CATALYSIS, 2018, 1 (07): : 490 - 500
  • [3] Critical Assessment of the Electrocatalytic Activity of Vanadium and Niobium Nitrides toward Dinitrogen Reduction to Ammonia
    Hoang-Long Du
    Gengenbach, Thomas R.
    Hodgetts, Rebecca
    MacFarlane, Douglas R.
    Simonov, Alexandr N.
    [J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (07) : 6839 - 6850
  • [4] Perovskites in catalysis and electrocatalysis
    Hwang, Jonathan
    Rao, Reshma R.
    Giordano, Livia
    Katayama, Yu
    Yu, Yang
    Shao-Horn, Yang
    [J]. SCIENCE, 2017, 358 (6364) : 751 - 756
  • [5] Transition metal oxynitride catalysts for electrochemical reduction of nitrogen to ammonia
    Ologunagba, Damilola
    Kattel, Shyam
    [J]. MATERIALS ADVANCES, 2021, 2 (04): : 1263 - 1270
  • [6] Vanadium oxynitrides as stable catalysts for electrochemical reduction of nitrogen to ammonia: the role of oxygen
    Pan, Jaysree
    Hansen, Heine Anton
    Vegge, Tejs
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2020, 8 (45) : 24098 - 24107
  • [7] Challenges and opportunities for nitrogen reduction to ammonia on transitional metal nitrides via Mars-van Krevelen mechanism
    Qiao, Zhi
    Johnson, Denis
    Djire, Abdoulaye
    [J]. CELL REPORTS PHYSICAL SCIENCE, 2021, 2 (05):
  • [8] A high-throughput study of oxynitride, oxyfluoride and nitrofluoride perovskites
    Wang, Hai-Chen
    Schmidt, Jonathan
    Botti, Silvana
    Marques, Miguel A. L.
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2021, 9 (13) : 8501 - 8513
  • [9] Over 56.55% Faradaic efficiency of ambient ammonia synthesis enabled by positively shifting the reaction potential
    Wang, Mengfan
    Liu, Sisi
    Qian, Tao
    Liul, Jie
    Zhou, Jinqiu
    Ji, Haoqing
    Xiong, Jie
    Zhong, Jun
    Yan, Chenglin
    [J]. NATURE COMMUNICATIONS, 2019, 10 (1)
  • [10] Acid-Stable Oxides for Oxygen Electrocatalysis
    Wang, Zhenbin
    Zheng, Ya-Rong
    Chorkendorff, Ib
    Norskov, Jens K.
    [J]. ACS ENERGY LETTERS, 2020, 5 (09) : 2905 - 2908
12