Influence of Ce3+ substitution on the structural, electrical and magnetic properties of Zn0.5Mn0.43Cd0.07Fe2O4 spinel ferrites

被引:24
作者
Ikram, Salma [1 ]
Jacob, Jolly [2 ]
Mahmood, K. [1 ]
Ali, A. [1 ]
Amin, N. [1 ]
Rehman, U. [1 ]
Arshad, M. Imran [1 ]
Nabi, M. Ajaz Un [1 ]
Javid, Kashif [1 ]
Ashfaq, A. [1 ]
Sharif, M. [1 ]
Hussain, S. [3 ]
机构
[1] Govt Coll Univ Faisalabad, Dept Phys, Faisalabad, Pakistan
[2] Abu Dhabi Univ, Coll Arts & Sci, Abu Dhabi, U Arab Emirates
[3] Univ Educ Lahore, Dept Phys, Div Sci & Technol, Lahore, Pakistan
关键词
Cerium substituted Mn-Zn-Cd ferrites; Co-precipitation method; XRD; DC electrical resistivity; M-H loop; DIELECTRIC-PROPERTIES; ELECTROMAGNETIC BEHAVIOR; CR FERRITES; ZN FERRITES; IONS; RESISTIVITY; DIVALENT;
D O I
10.1016/j.physb.2019.411764
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
In this paper, the effect of Ce3+ ions addition on the microstructure, electrical and magnetic behaviour of Cadmium doped Mn-Zn ferrites was investigated. A series having composition Zn(0.5)Mn(0.43)Cd(0.07)Ee(2-y)CeyO(4)(y = 0.0-0.7) was synthesized by wet chemical route. X-Ray Diffraction (XRD) analysis showed that prepared particles having size in nano-regime having cubic spinel structure with preferred (311) plane. Weakening of (311) plane intensity and emergence of secondary phase with Ce3+ ion concentration verified the substitution of Ce3+ ions in the spinel lattice of ferrite. The crystallite size varied between 46.4 and 67 nm as the concentration of Ce3+ ions increased from x = 0.0-0.7. Temperature and composition dependent electrical resistivity and activation energy values were calculated by current-voltage (I-V) characteristics in the temperature range 423-823 K by two probe method. It was observed that DC Resistivity and activation energy of synthesized nanoparticle ranges between 10(9) to similar to 10(19) Ohm cm and 11.78-2.56 eV respectively with increasing the concentration of Ce3+ ions. MH curves of prepared samples showed the paramagnetic nature of spinel feerites. The reported data suggested that these particles promising candidates for high-frequency applications.
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页数:5
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