Transition-Metal-Catalyzed C-H Alkylation Using Alkenes

被引：914
|
作者：
Dong, Zhe [1 ,2 ]
Ren, Zhi [2 ]
Thompson, Samuel J. [2 ]
Xu, Yan [1 ,2 ]
Dong, Guangbin [1 ,2 ]
机构：
[1] Univ Chicago, Dept Chem, 5735 S Ellis Ave, Chicago, IL 60637 USA
[2] Univ Texas Austin, Dept Chem, Austin, TX 78712 USA
来源：
CHEMICAL REVIEWS | 2017年 / 117卷 / 13期
关键词：
CARBON-HYDROGEN BONDS; BETA-KETO-ESTERS; ACTIVATED METHYLENE-COMPOUNDS; C(SP(3))-H ALPHA-ALKYLATION; ASYMMETRIC INTERMOLECULAR HYDROARYLATION; BRANCHED-SELECTIVE HYDROARYLATION; ANTI-MARKOVNIKOV HYDROARYLATION; STEP-GROWTH COPOLYMERIZATION; FRIEDEL-CRAFTS ALKYLATION; UNACTIVATED OLEFINS;
D O I：
10.1021/acs.chemrev.6b00574
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Alkylation reactions represent an important organic transformation to form C-C bonds. In addition to conventional approaches with alkyl halides or sulfonates as alkylating agents, the use of unactivated olefins for alkylations has become attractive from both cost and sustainability viewpoints. This Review summarizes transition-metal-catalyzed alkylations of various carbon hydrogen bonds (addition of C-H bonds across olefins) using regular olefins or 1,3-dienes up to May 2016. According to the mode of activation, the Review is divided into two sections: alkylation via C-H activation and alkylation via olefin activation.
引用
收藏
页码：9333 / 9403
页数：71
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