Dehydration of glucose to levulinic acid over MFI-type zeolite in subcritical water at moderate conditions

被引：62

作者：

Zeng, Wei ^{[1
]}

Cheng, Dang-guo ^{[1
]}

Zhang, Huanhuan ^{[1
]}

Chen, Fengqiu ^{[1
]}

Zhan, Xiaoli ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem & Biol Engn, Hangzhou 310027, Zhejiang, Peoples R China

来源：

REACTION KINETICS MECHANISMS AND CATALYSIS | 2010年 / 100卷 / 02期

关键词：

Zeolite; MFI; Glucose; Levulinic acid; Mesoporosity; HETEROGENEOUS ZIRCONIUM; ORGANIC-ACIDS; SOLID-ACID; D-FRUCTOSE; CATALYSTS; 5-HYDROXYMETHYL-2-FURALDEHYDE; KINETICS; SUCROSE; BIOMASS;

D O I：

10.1007/s11144-010-0187-x

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The catalytic properties of a novel MFI-type zeolite with different SiO(2)/Al(2)O(3) ratio in the dehydration of glucose to levulinic acid (LA) were investigated in this work. The results demonstrate the strength of acidic sites and the mesoporosity of the zeolites have significant effects on LA formation.

引用

页码：377 / 384

页数：8

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