Schiff-base compartmental macrocyclic complexes

被引:200
作者
Atkins, AJ
Black, D
Blake, AJ
MarinBecerra, A
Parsons, S
RuizRamirez, L
Schroder, M
机构
[1] UNIV EDINBURGH, DEPT CHEM, EDINBURGH EH9 3JJ, MIDLOTHIAN, SCOTLAND
[2] UNIV NOTTINGHAM, DEPT CHEM, NOTTINGHAM NG7 2RD, ENGLAND
[3] NATL AUTONOMOUS UNIV MEXICO, FAC QUIM, DEPT QUIM INORGAN, MEXICO CITY 04510, DF, MEXICO
关键词
D O I
10.1039/cc9960000457
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis of a range of new compartmental macrocyclic complexes based on 2,6-diformyl and -diketo phenol groups is described. The metal-free ligands have been prepared and structurally characterised for the first time, and this has led to the synthesis of novel cubane and platinum-group metal complexes. The synthesis of related dithiophenolato-bridged compartmental complexes of Ni-II Cu-II and Zn-II has been achieved and the relevance of these species to metalloproteins is discussed.
引用
收藏
页码:457 / 464
页数:8
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