Cyclic carbopalladation of alkynes terminated by carbonylative amidation

被引：24

作者：

Coperet, C ^{[1
]}

Ma, SM ^{[1
]}

Sugihara, T ^{[1
]}

Negishi, E ^{[1
]}

机构：

[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

来源：

TETRAHEDRON | 1996年 / 52卷 / 35期

关键词：

D O I：

10.1016/0040-4020(96)00640-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Termination of cyclic carbopalladation of alkynes via carbonylative lactamization can be achieved more satisfactorily with alkenyl or aryl halides containing an omega-carboxamido or omega-sulfonamido group than with those containing an omega-amino group. The method appears to be generally satisfactory for the preparation of fused cyclic systems consisting of six-membered rings, while the other cases require further development. Copyright (C) 1996 Elsevier Science Ltd

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页码：11529 / 11544

页数：16

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