Synthesis of acetamides using CO2, methanol, H2 and amines

被引：16

作者：

Zhang, Jingjing ^{[1
,2
]}

Qian, Qingli ^{[1
]}

Wang, Ying ^{[1
,2
]}

Bediako, Bernard Baffour Asare ^{[1
,2
]}

Cui, Meng ^{[1
,2
]}

Yang, Guanying ^{[1
]}

Han, Buxing ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Colloid Interface & Chem Thermodynam, CAS Res Educ Ctr Excellence Mol Sci,Inst Chem, Beijing 100190, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

GREEN CHEMISTRY | 2019年 / 21卷 / 02期

基金：

中国国家自然科学基金;

关键词：

CARBON-DIOXIDE; N-FORMYLATION; FORMIC-ACID; ACETIC-ACID; HYDROGENATION; HYDROCARBOXYLATION; CATALYSIS; COMPLEX;

D O I：

10.1039/c8gc03476a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we report the synthesis of acetamides from CO2, methanol, H-2 and corresponding amines, which is a new route used to synthesize acetamides. It was found that the Rh catalyst with LiI/LiCl as promoters could effectively catalyze this reaction. Interestingly, no ligand was required and amine substrates played a role in accelerating the reaction.

引用

收藏

页码：233 / 237

页数：5

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