Transition-Metal-Catalyzed Denitrogenative Transannulation: Converting Triazoles into Other Heterocyclic Systems

被引：567

作者：

Chattopadhyay, Buddhadeb ^{[1
]}

Gevorgyan, Vladimir ^{[1
]}

机构：

[1] Univ Illinois, Dept Chem, Chicago, IL 60607 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 04期

基金：

美国国家卫生研究院;

关键词：

cyclization; nitrogen heterocycles; transition metals; transannulation; synthetic methods; BETA-TURN MIMICS; ANNULATION REACTIONS; EFFICIENT SYNTHESIS; SYNTHETIC UTILITY; ALKYNE INSERTION; CLICK-CHEMISTRY; SULFONYL AZIDE; INHIBITORS; DIAZOIMINE; INDOLES;

D O I：

10.1002/anie.201104807

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transition metal catalyzed denitrogenative transannulation of a triazole ring has recently received considerable attention as a new concept for the construction of diverse nitrogen-containing heterocyclic cores. This method allows a single-step synthesis of complex nitrogen heterocycles from easily available and cheap triazole precursors. In this Minireview, recent progress of the transition metal catalyzed denitrogenative transannulation of a triazole ring, which was discovered in 2007, is discussed.

引用

页码：862 / 872

页数：11

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